Method for the recovery and purification of gaseous uf6 from gaseous mixtures and uf7no2 and uf7no2 products produced thereby



6 .4 8, 9 s 3W 0 ,S 3U m0.. AN Mw., IEQ zmnomml OD OO@ OOw OOO OON OQ O09 OO@ OOON OOOm wm. o IO MNB .1o. RNFE 9 JFUw 1 om EMDD l UNOMQ l @FARE 5oz Ds Rt llllll ommm WWvTd O uw M .E \l Pwmm n C U mm Pf n o@ ES A F RM wm om D O H \J| \Lll\\l|\|// w (SGAHHk Q f June 19, 1962 INVENTOR. Pearl R. Ogle, Jr.

BY /KM @J ATTORNEY United States aret- METHOD FOR THE'RECOVERY -AND PURIFICA- TION OF'GSEOUS UF6 FROM GASEOUS MIX- TURES AND UFqNO AND UFqNOz PRODUCTS PRODUCED -THEREBY Pearl yR. Ogle, Jr., Chillicothe, Ohio, assignor to the iUnited tStates if/Americay as represented by the United States 'Atomic Energy Commission Filed/Oct. 9, rv1961, Ser. No. 143,986 A8 Claims. (Cl. zii-14.5)

The present invention relates'toa new and useful class l of chemical reactions `involving gaseous uranium 'hexaiiuoride .and to a new and useful'method of recovering fand/or Apurifying Ygaseous uranium hexafluoride values from la gaseous mixture containing said values by utilizing said reactions.

There are many Ways of synthesizing uranium hexauoride. A number of methods for the preparation of uranium hexafluoride are disclosed in chapter VIII of The Chemistry of Uranium by Katz and Rabinowitch, National Nuclear Energy Series, VIII-V, McGraw-Hill, 195.1. Regardless of its source, -a synthesized UF6 prod- Y uct is usually found as a component of aV gaseous mixture from which it must be separated to a high degree of purity. The most common volatile impurities in a gaseous stream containing UF6 include, among others, gase-l ous iluorine, chlorine, bromine, oxygen, hydrogen chloride and inert gases such as nitrogen, argon, hydrogen iiuoride, carbon dioxide, and carbon monoxide.'

It is accordingly an object of this invention to provide a method of removing and purifying gaseous UF6 from a gaseous stream.

Another object of this invention is to provide a method of converting gaseous UF6 into a form from which it can easily be regenerated.

A further object of the invention is to provide a useful and novel class of chemical reactions and uranium cornpounds resulting therefrom whereby the preceding objects can be achieved.

With these and other objects in mind the present invention comprises in its method aspect, the steps which comprise reacting a gaseous stream containing UF6 and extraneous gaseous impurities at a temperature in the range 100 to 50 C. with a compound selected from Ythe class nitrosyl fluoride and nitryl fluoride and thereafter separating a solid uranium fluoride product having an empirical formula UF7N(O)X, where x is a number from ll to 2.

The following examples will serve to illustrate the preparation of the compounds of this invention.

Example I UFetrl-NOFm UFiNO An elemental analysis ofthe solid was conducted and the following results obtained. Theory based on UFfINO: U, 59.36; F, 33.16;*N, 3.49. Found: U, 58.98;F, 29.66; N, 3.58.

An infrared spectrum` of the solid was obtained and is shown in the accompanying FIGURE. For purposes of comparison, the principal characteristic absorption peaks yso 3,039,846 "Patented .lune 19, 1962 of UF6 are superimposed. The absorption bands at 2320 and 2318, and'549 to 510 crn.-1 are. attributed to vthe NO+ and UFqi'ons,respectively, this indicating-that kthe compound UFqNO is a 1:1 addition complex having a composition NOF.UF6. This compound has a vapor pressure of less than l mm; Hg'at 25 C. with the Vapor over the solid comprising approximately equal molar quantities lof uranium hexafluoride and nitrosyl fluoride.

Example II An infrared spectrum of this compound revealed an absorption based at 2374cm1 which is indicative of the NO2+ ion. Characteristic absorption Ybands of NOZF and UE6 werealso observed.

An elemental analysis ofthe compound was obtained and compared with elemental composition for-UFqNO.

Theory'based on'UFqNOZ: U,'57.'08; F, 31.89;v N, 3.36.

Found: U, 57.23; F, 28.51; N, 3.64.

Based on the infrared spectrum and chemical analysis, it wasconcluded that the compound had the composition of a 1:1 addition complex NO2F.UF6. The vapor above this compound comprises approximately equal molar quantities of uranium hexauoride and nitryl fluoride NOZF. The reaction of UF6 with either nitrosyl uoride or nitryl iluoride effects no change in the uranium oxidation state of UF6. Thus when either UFqNO orUF7NO3 is dissolved in water, it results in a solution containing hexavalent uranium, as the uranyl ion, and nitric acid. This is to be compared with the reaction product of NO or NO2 with UF6 which yields a solid UF6N(O)X, where x is a number from 1 to 2. Compounds of the class UF6N(O)x (which are disclosed and claimed in application S.N. 19,132, of common assignee) when dissolved in water, give a mixture of tetravalent uranium and hexavalent uranium whileUF6, UF-,NO and UFqNOZ dissolved in water yield the hexavalent uranyl ion only.

In order to utilize the compounds of this invention for the purposes of recovering gaseous UF6 from a gas mixture, it is only necessary to react the mixture with nitrosyl or nitryl uoride at a temperature not exceeding about 40 C. and preferably at a pressure below the vapor pressure of such compounds. The UF6 will react virtually immediately to 4form the solid addition compound. The solid compound is allowed to settle or is filtered olf and the volatile contaminants are removed by purging or under vacuum. This method is particularly valuable for recovering uranium hexailuoride from gas streams containing low concentrations or traces of uranium hexauoride. As between using nitrosyl. or nitryl fluoride,

nitrosyl uoride is the preferred reagent since it forms a compound of lower volatility.

The unique .advantage in using these compounds to recover UF6 is that the uranium does notrundergo a valence change. Moreover, the resultant compounds can easily be decomposed, preferably in vacuum, at slightly elevated temperatures,y over about 50' C. to regenerate the desired UF6. This is to be compared with other methods forstripping UF6 where chemical traps are usedV Y Essentially all the UF6 can `be removed by passing the UF6 containing to strip the last traces`of UF6 from gases.

gas through a bedlof calcium sulfate, calcium'uoride oractivated alumina or by scrubbing the gas with water,

but expensive wet processing methods are necessary to recover the uranium from the solids.

The reaction between UF6 and nitrogen oxyhalides formula UFqNO.

, evidenced by the presence of U+4 in aqueous solutions of u t UFGNO. Other oxyhalides follow the reaction pattern of t t nitrosyl chloride ratherthan nitrosyl fluoride to eiect` t at least a partial reduction of the hexavalent uranium of" UF6. All ofthe nitrogen oxyhalides, however, may be used to recover and purify UF6 from a UF6 containingi gas stream. The choice of oxyhalide will depend on the uranium oxidation state desired in the iinal product` If the hexavalent uranium is desired to be retained, then the choice will be nitrosyl and/or nitryl fluoride. If solid uranium compound whereinthe uranium is in a lower oxidation state is desired,V the choice should be nitrosyL or nitryl chloride,l bromide or iodide.

Having thus described my invention, I claim:

l. A new uranium compound 'having the formula UF7N(O)x where x is a Whole number from 1 to 2.

2. Anew uranium compound having the `empirical 3. A new uranium compound having the empirical formula UFqNO2.

4. A method for recovering uranium hexauoride from a gaseous mixture containing said uranium hexauoride .4 t and extraneous gaseous impurities the Vsteps which comprise reacting said mixture at a temperature in the Y range of -100 to 200 `C."with oxyhalides of nitrogen to form a solid addition compound of uranium hexafluoride, purging the atmosphere above with resultant compound to remove said extraneous gases, and thereafter isolating ,the said solid uranium compound. o o

5. lIn a method of recovering uranium hexauoride from a gaseous mixture containing said uranium hexauoride and extraneous gaseous impurities, the `steps which comprise reactinglsaid mixture with a nitrogen oxyiiuoride at a temperature in the range -100 to 50 C. to thereby form a solid` compound having the empirical formula U1-`1N(O)`X Where x is a number from 1 to 2.

6. The method accordingto claim 5, wherein the nitrogen oxyuoride is nitrosyl fluoride. i

7. The method according to claim 5, wherein the nitrogen oxyiluoride is nitryl uoride.

8. A method of separating uranium hexauoride from a gaseous mixture containing said uranium hexafiuorde and extraneous gaseous impurities which comprises reacting said mixture with nitrosyl chloride and thereafter recovering a solid compound having the formula i UFNO-nitrosylium hexauorouranate. 

1. A NEW URANIUM COMPOUND HAVING THE FORMULA UF7NO(O)X WHERE X IS A WHOLE NUMBER FROM 1 TO
 2. 4. A METHOD FOR RECOVERING URANIUM HEXAFLUORIDE FROM A GASEOUS MIXTURE CONTAINING SAID URANIUM HEXAFLUORIDE AND EXTRANEOUS GASEOUS IMPURITIES BY THE STEPS WHICH COMPRISE REACTING SAID MIXTURE AT A TEMPERATURAE IN THE RANGE OF -100 TO 200*C. WITH OXYHALIDES OF NITROGEN TO FORM A SOLID ADDITION COMPOUND OF URANIUM HEXAFLUORIDE, PURGING THE ATMOSPHERE ABOVE WITH RESULTANT COMPOUND TO REMOVE SAID EXTRANEOUS GASES, AND THEREAFTER ISOLATING THE SAID SOLID URANIUM COMPOUND. 